Gas phase fluorination is an innovative and practically applicable process for durable modification of polymer surfaces. In contrast to coating technologies, the surface is not coated, but modified. The fluorination process produces chemically stable fluorine compounds with covalent bonds that do not rely on weak Van-der-Waals-bondings, as most coatings do.
Depending on the process parameters, fluorination can influence various surface properties. A distinction is made between fluorination without oxygen, and with oxygen (oxy-fluorination).
The process can modify the following surface properties:
- Permanent hydrophilic
- Long-lasting activation of non-polar surfaces (for improved adhesion)
- Improved barrier against of fuel and gas permeation
- Reduced friction for elastomers and TPE
- Reduced migration of polymer additives
The surface is modified through the reaction of fluorine gases; which strongly react with hydrogen containing substances, thereby forming hydrogen fluoride. The free functional sites can react with fluorine, oxygen, or by crosslinking the polymer. Calcium carbonate absorbs hydrogen fluoride and residual fluorine, to protect operators and the environment.
A special advantage of the gas phase fluorination is the efficient treatment of complex geometries. Even the surfaces in holes and undercuts are treated completely and homogeneously.
INNOVENT has a close cooperation with users, contract treatment companies, and the equipment construction company Fluor Technik System GmbH.